Life cycle assessment of biodiesel production from waste cooking oil in western australia abstract biodiesel derived from waste cooking oil wco is considered highly environmental sustainable since wco is a waste product which has been recycled to a transportation fuel in western australia. Biodiesel is synthesized by direct transesterification. Biodiesel from food waste and used cooking oil the. Jan 24, 2020 how to prepare used cooking oil for biodiesel. All reactions are carriedout under atmospheric pressure and 1500 rpm of agitation.
Small scale biodiesel production table of contents 1. Conversion of waste cooking oils into environmentally. Comparative performance analysis of diesel and waste cooking. Onestep alkaline koh catalytic process was employed in the production of the. The study deals with the used cooking oil collection industry that lies at the intersection of two very promising sectors of the economy, the biofuels biodiesel industry and the waste management industry. The process of converting waste vegetable oil wvo to biodiesel is essentially the same as that of converting virgin vegetable oil, but working with wvo requires a few extra steps. Recent strategy of biodiesel production from waste cooking. It is the catalyst for transesterification and works by cracking the vegetable oil molecules, splitting the triglyceride from the hydrocarbons and shortening the carbon chain isopropyl alcohol. Also waste oils and fats used cooking oils are used as a good feedstock, its costs approaches half of the cost of virgin oil 4. Biodiesel is generally reported as being more costly than conventional diesel fuel. Production and characterization of heterogeneous catalyst.
Pdf production of biodiesel from used cooking oil find, read and cite all the research you need on researchgate. The transesterification of waste cooking oil to biodiesel. Pdf alkaline transesterification of waste cooking oil to. Waste cooking oil to biodiesel conversion for space heating applications by daniel j. These sectors are heavily influenced by the guidelines and the incentives provided by the regulatory framework. In this study biodiesel was made from used cooking oil and methanol using the transesterification method with koh catalyst.
Waste oil supply clean drums for strained oil finished fuel glycerin containers, beakers, buckets of various sizes for chemical pouring, waste glycerin, and waste oil emulsion safety equipment face shield, gloves, apron storage area for finished fuel chemicals koh or naoh methanol. The aim of this article is to evaluate the potential use of biodiesel produced from waste cooking oil in mexico city. The parameters affecting biodiesel production process such as alcohol to oil molar ratio, catalyst concentration, the presence of tetrahydrofuran thf as a cosolvent, and the volumetric flow rates of. Biodiesel production from waste cooking oil carlos a.
Business plan for the development of a used cooking oil. Waste cooking oil makes bioplastics cheaper sciencedaily. According to this directive, member states ms shall take measures to encourage the separate collection and the treatment of bio waste in a way that fulfils a high level of environmental protection. Biodiesel production optimization from waste cooking oil. The production of biodiesel from waste vegetable oils through its pretreatment followed by transesterification process in presence of methanol was investigated using a km micromixer reactor. But the main problem of using waste cooking oil is the existence of free fatty acid as the by product in transesterification process. Since lipase catalysts are much expensive, the usage of lipase in biodiesel production is. Biodiesel can be defined as fatty acid methyl esters fame derived from the transesterification of triglycerides vegetable oils or animal fats with alcohol and. Sierra national university of colombia, colombia 1. At illinois state university, waste fryer oil from residential dining centers is being converted into fuel for use in campus fleet vehicles. The dominant biodiesel feedstock for biodiesel consumed in the uk is used cooking oil uco, defined as the purified oils and fats of plant and animal origin that have been used to cook food. Transesterification, waste cooking oil, heterogeneous catalyst, biodiesel. Bruton in partial fulfillment of the requirements for the degree of master of science in sustainable systems and accepted on behalf of the rochester institute of technology by the thesis committee.
Pdf production of biodiesel from waste cooking oil and. Waste cooking oiltobiodiesel conversion for space heating. These includes linseed oil, palm seed oil, waste cooked vegetable oil, sunflower seed oil, cotton seed oil, cooking seed oil and animal fats 7, 8, 9. Biodiesel can be used in dieselfueled vehicles without any modification of the engine. Hence, the recent focus rely on using waste cooking oil as the substantial feed stocks for biodiesel production. For serving better quality food, they usually throw this waste cooking without any treatment 2,4. A biodegradable, combustible fuel made from vegetable oils andor animal fats. Performance analysis of biodiesel derived from waste. The expense of waste cooking oil is approximately rs. In this work, biodiesel ethyl ester was prepared from waste cooking oil.
Some estimates suggest waste vegetable oil generation of 500,000 litres per day 182,000 tonnes per annum in punjab alone. Dont use a gas burner for this or any other stage of the biodiesel. Physicochemical analysis of waste cooking oil reveals the acid value 3. Everywhere in the world, there is an enormous amount of waste lipids generated from restaurants, food processing. Feasibility study of biodiesel and waste vegetable oil at. Biodiesel production from waste cooking palm oil and environmental impact analysis 187 when vegetable oil or animal fat is reacted chemically with an alcohol to produce fatty acid alkyl esters transesterification somporn and shabbir, 2009. Synthesis of biodiesel from vegetable oil using supported. Review of the production of biodiesel from waste cooking oil using. Waste cooking oil wco disposal is also a problem because it cannot reuse for cooking, which causes undesirable affect on human health. Emission characteristics for waste cooking oil biodiesel. The reaction temperature was 60 oc with 250rpm mechanical stirring. Biodieselsfrom waste cooking oil life cycle emission of carbon dioxide and particulate matter is much lower than that from diesel the life cycle analysis indicates that the use of biodieselas an alternative automotive fuel is acceptable from the environmental point of view. Use of low cost feedstocks such as waste cooking oil wco should help make biodiesel competitive in price with petroleum diesel.
Waste cooking oil is a promising alternative for producing biodiesel because it is a cheaper raw material that also avoids the cost of waste product disposal and treatment 1. Uk produces over 200,000 tons of waste cooking oil per year 19. Biodiesel s from waste cooking oil life cycle emission of carbon dioxide and particulate matter is much lower than that from diesel the life cycle analysis indicates that the use of biodieselas an alternative automotive fuel is acceptable from the environmental point of view. The purpose of this research is to produce biodiesel from waste cooking oils in the laboratory and compare the quantity and quality of products made from domestic waste cooking oil, restaurant cooking oil and fresh. One day, the world is going to run out of petroleum. Performance of a diesel engine fueled by waste cooking oil. In the present study biodiesel was synthesized from waste cook oil wco by threestep method and regressive analyzes of the process was done.
Sample of waste cooking oil the waste cooking oil is generated from the fried food, which need large amounts of oil because it requires the full immersion of food at temperatures greater than 180 c. Biodiesel may be used in any diesel automotive engine in its pure form or blended with petroleumbased diesel. Conversion of waste cooking oil to biodiesel 11 biodiesel feedstock competes with the use of land for food production. Synthesis of biodiesel from secondused cooking oil sciencedirect.
Introduction biodiesel refers to all kinds of alternative fuels derived from vegetable oils or animal fats. Alternate fuels should be economically attractive in order to compete with currently used fossil fuels. The use of waste cooking oil as biodiesel feedstock reduces the cost of biodiesel production. Cooking oil is used in substantial quantity for food frying either in home, restaurants or in food industry. Additionally, the use of waste fried cooking oil wfco as a reactant for biodiesel plant helps in disposing this waste and reduction of feedstock production. Recycling of waste cooking oils wco to biodiesel production. Waste cooking oil is a potential replacement for vegetable oils in the production of biodiesel. Pdf biodiesel refers to all kinds of alternative fuels derived from vegetable oils or animal fats. Production of biodiesel from waste vegetable oil publish.
Biodiesel and waste vegetable oil are both produced or refined from used vegetable oil, though each with different degrees of difficulty and involvement. The use of waste cooking oil as a biodiesel source has a potential to reduce co2, particulate matter and other greenhouse gases as the carbon contained in biomassderived fuel is largely biogenic and renewable. To minimize the biofuel cost, in recent days waste cooking oil was used as feedstock. Hence, use of waste cooking oils instead of raw oils, to produce biodiesel, is an effective method to bring down the cost of raw material.
Some people have expressed interest in using straight vegetable oil svo, or waste oils from cooking and other processes, as fuel. A twostep transesterification process was used to produce biodiesel alkyl ester from high free fatty acid ffa waste cooking oil. The waste framework directive 200898ec classifies used cooking oil uco in the category edible oil and fat ewc 20 01 25. Nov 25, 2019 you can also make biodiesel from waste cooking oil, but that is a little more involved, so lets start with the basics. How to make biodiesel from vegetable oil thoughtco. Applications of waste cooking oil other than biodiesel. Pdf biodiesel production from waste cooking oil in. Small scale biodiesel production feasibility report.
Costs in a small plant would be about 10 cents per litre higher than the tallow cost, although, when using waste cooking oil, this additional cost would be largely offset by the cheaper feedstock. The recipe for making biodiesel from virgin vegetable oil, using base as a catalyst, is simple. Hence, the recent focus rely on using waste cooking oil as the substantial feed stocks for. Diesel engines are widely used for propulsion on large ships, which has the undesired characteristic of generating large amounts of harmful emissions. Physical property prediction for waste cooking oil biodiesel.
Biodiesel production from waste cooking oil using sulfuric. By comparison, diesel consumption in pakistan is 7 million tonnes. Synthesis and characterization of biodiesel from waste. As large amounts of waste cooking oils are illegally dumped into rivers and landfills, causing environmental pollution 20, the use of waste cooking oil to produce biodiesel as. The use of a heterogeneous catalyst can make the production process costeffective and environmentally friendly. Apr 19, 2017 in this study, biodiesel was produced using waste cooking oil that was discarded as a waste in the environment. How biodiesel fuel is made from waste vegetable oil how this fuelmaking process can be adjusted to utilize waste oils from different. Pdf biodiesel production from waste cooking oil researchgate. Develop an organized waste cooking oil disposal system. Biodiesel is a combustible fuel that is biodegradable and made from vegetable oil or animal fat. Optimization of biodiesel production from waste cooking oil. The properties of the feedstock were determined using standard astm methods.
As crude oil price reach a new high, the need for developing alternate fuels has become acute. Nov 21, 20 oil which has been used for cooking will required more of the reactive agents and methanol than fresh oil. In most waste cooking oil, the level of free fatty acids is above 2 wt. This work investigated the potential of producing biodiesel from waste cooking oil wco collected from eateries and fast food restaurants in awka, anambra nigeria. Besides, it reduces the need to use land for biodiesel producing crops. Bioplastics that are naturally synthesized by microbes could be made commercially viable by using waste cooking oil as a starting material. Moreover, the removal of these catalysts after the reaction is complete needs the washing of biodiesel with water which might result in loss of fatty acid alkyl esters, energy.
The presence of too many free fatty acids will retard or stop the reaction, which produces biodiesel, so it is necessary to deduce the exact amount of alkali sodium hydroxide needed to neutralize the acids. Materials for making biodiesel 1 liter of new vegetable oil e. These days, many used cooking oils from restaurants were reused by street sellers to fry their food. Since waste cooking oil contains high ffa content, a twostep process, acid esterification followed by alkali transesterification was employed using methanol, sulfu. Accordingly to the high temperatures are generated changes in its chemical and physical composition. The production of biodiesel from waste vegetable oil offers significant benefits on economic. In some places, uco from restaurants were reused by street sellers to fry their food,this waste oil is termed as second used cooking oil can also be utilized by converting to biodiesel3.
The results have shown that all the three factors have affected the methyl ester yield and a significant. Pdf biodiesel from waste cooking oil in mexico city. As large amounts of waste cooking oils are illegally dumped into rivers and landfills, causing environmental pollution 19, the use of waste cooking oil to produce biodiesel as petrodiesel. An improvement in biodiesel production from waste cooking oil by. Use a cooking thermometer to monitor the temperature. Production of biodiesel from waste cooking oil using cao. Moreover, the price of edible plant and vegetable oils is usually higher than petro diesel.
Since the bse crisis european uco is classified as a waste that is no longer fit for human or animal. Waste water from the fuel washing process approximately 1 gallon of water for every gallon of biodiesel glycerin is drained off at the end of the fuel production process approximately 1 gallon for every 3 gallons of biodiesel both the waste water and glycerin have small amounts of methanol in them. It is alkali catalyzed reaction which involves waste cooking oil, methanol, and potassium hydroxide. Its price is approximately half that of virgin oil 11 and the biodiesel fuels made from waste cooking oil have similar. The waste snail shell was screened to determine its efficiency as heterogeneous catalyst for biodiesel production via transesterification reaction. Waste vegetable oil is one of the sources of biodiesel and of all the other sources, it would be best in tropical countries. Microsoft powerpoint biodiesel production from waste cooking oil a renewable blend for diesel engines compatibility mode author.
Waste cooking oil as an alternate feedstock for biodiesel. Biodiesel is known for its less polluting, renewable, and biodegradable properties. This would reduce environmental contamination and also. Boyce bioenergy laboratory, programm of biotechnology, institute of biological sciences, faculty of science, university of malaya, kuala lumpur, malaysia abstract hossain, a. Waste cooking oil to biodiesel automated fuel pump project. Oilseed plants are used for the production of biodiesel through the process called transesterification reaction which is a process by which alcohol reacts with vegetable oil in the presence of. Therefore, the use of waste cooking oil should greatly reduce the cost of biodiesel because waste oil is available at a relatively low price. The transesterification process was implemented to extract the biodiesel, and this process was optimized and standardized by selecting three different parameters. In the present work, 94% of waste cooking oil sample is converted to biodiesel.
The study focus on the physical and chemical properties of waste cooking oil wco, transesterification and production of biodiesel from wco. The blending of biodiesel in diesel fuel became mandatory when the biofuels act of 2006 also known as republic act 9367 was. Optimized biodiesel production from waste cooking oil wco. The cost of waste cooking oil varies from free to 60% less than raw vegetable oils, depending on the source, availability and quantity 41.
Pdf waste cooking oil to biodiesel fuel ahmad j al. Biodiesel production from locally sourced restaurant waste. A comparative study of biodiesel production from waste cooking oil using sulfuric acid twostep and microwaveassisted transesterification onestep was carried out. Production of biodiesel from waste vegetable oil via km. Abstract biodiesel was produced from waste cooking oil and virgin oil through transesterification reaction in batch process. International journal of materials science and engineering. Characterization of biodiesel produced from waste cooking. The produce or yield from waste cooking oil wco is approximately 90%.
A direct injection diesel engine fueled by a diesel biodiesel blend from waste cooking oil up to b100 a blend of 100% biodiesel content indicated a combustion efficiency rise by 1. Quality characteristics of biodiesel produced from used cooking oil. Catalysts used in this process are usually acids, base, and lipase. Pdf present study describes optimized production of waste cooking oil biodiesel using chemical and enzymatic transesterification. It is conventionally produced by the alkalicatalyzed transesterification of triglycerides. Hence, the total waste cooking oil produced in libya could be approximately 1,650 ty. Biodiesel from used cooking oil free download as powerpoint presentation. Cost of biodiesel produced from virgin vegetable oil through transesterification is higher than that of fossil fuel, because of high raw material cost. Biodiesel from householdrestaurant waste cooking oil wco. Biodiesel from used cooking oil biodiesel diesel fuel.
Alkaline transesterification of waste cooking oil to biodiesel. The environmental issues associated with the use of fossilbased energy sources have informed the search for more sustainable energy alternatives. The processing cost of biodiesel is the main issue to commercialization of the product. The need for energy is increasing continuously due to. Synthesis of biodiesel from secondused cooking oil. Transesterification and production of biodiesel from waste. Biodiesel production from waste cooking oil journal of chemical. Conversion of waste cooking oil to biodiesel catalyst is limited only for refined vegetable oil with less than 0. According to this directive, member states ms shall take measures to encourage the separate collection and the treatment of biowaste in a way that fulfils a high level of environmental protection.
Nov 27, 2015 using waste cooking oil to produce biodiesel provides a suitable profitable way to eliminate the raw materials of gutter oil. Biodiesel production from waste cooking oil in laboratory scale article pdf available in applied mechanics and materials 448453 january 2014 with 4,941 reads how we measure reads. Biodiesel is a diesel fuel that is made by reacting vegetable oil cooking oil with other common chemicals. To reduce these emissions, some alternative fuel was developed and used in a marine diesel engine.
Waste cooking oil is one of the alternative sources among other higher grade or refined oil7 waste cooking oil is easy to collect from other industries such as domestic usage and restaurant7 and also cheaper to produce in small quantities than the refined oil. It is desirable as an alternative to petroleum fuel because it uses renewable resources that. In this lab, we will be starting with 200 ml of vegetable oil. Due to the depletion of world petroleum reserves and increasing environmental concerns, the interest. Life cycle assessment of biodiesel production from waste. In this work, we evaluated two catalysts, znozeolite and pbozeolite, for the synthesis of biodiesel using. Institute of environmental sustainability biodiesel labs. The transesterification of waste cooking oil to biodiesel not only solves the problem of waste oil treatment but also replaces partially or fully nearly one thousand million tons of diesel used annually by the world. In china, waste cooking oil is a potential low cost biodiesel feedstock.
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